Czech J. Food Sci., 2007, 25(4):159-174 | DOI: 10.17221/687-CJFS
Fluorescence spectroscopy and chemometrics in the food classification - a review
- Institute of Analytical Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technology, Bratislava, Slovak Republic
This review deals with the last few years' articles on various fluorescence techniques (conventional, excitation-emission matrix, and synchronous fluorescence spectroscopy) as a tool for the classification of food samples. Chemometric methods as principal component analysis, hierarchical cluster analysis, parallel factor analysis, and factorial discriminate analysis are briefly reminded. The respective publications are then listed according to the food samples: dairy products, eggs, meat, fish, edible oils, and others.
Keywords: chemometrics; fluorescence spectroscopy; food analysis
Published: August 31, 2007 Show citation
References
- Andersen Ch.M., Wold J.P., Mortensen G. (2006): Light-induced changes in semi-hard cheese determined by fluorescence spectroscopy and chemometrics. International Dairy Journal, 16: 1483-1489.
Go to original source...
- Aubourg S.P., Medina I. (1999): Influence of storage time and temperature on lipid deterioration during cod and haddock frozen storage. Journal of the Science of Food Chemistry, 79: 1943-1948.
Go to original source...
- Bertrand D., Scotter C.N.G. (1992): Application of multivariate analyses to NIR spectra of gelatinized starch. Applied Spectroscopy, 46: 1420-1425.
Go to original source...
- Blumberg W.E., Doleiden F.H., Lamola A.A. (1980): Hemoglobin determined in 15 microL of whole blood by "front-face" fluorometry. Clinical Chemistry, 26: 409-413.
Go to original source...
- Bro R. (1997): PARAFAC. Tutorial and applications. Chemometrics and Intelligent Laboratory Systems, 38: 149-171.
Go to original source...
- Cheikhousman R., Zude M., Bouveresse D.J.-R., Rutledge D.N., Birlouez-Aragon I. (2004): Fluorescence spectroscopy for monitoring extra virgin olive oil deterioration upon heating. Czech Journal of Food Sciences, 22: 147-150.
Go to original source...
- Christensen J., Miquel Becker E.M., Frederiksen C.S. (2005): Fluorescence spectroscopy and PARAFAC in the analysis of yogurt. Chemometrics and Intelligent Laboratory Systems, 75: 201-208.
Go to original source...
- Duflos G., Le Fur B., Mulak V., Becel P., Malle P. (2002): Comparison of methods of differentiating between fresh and frozen-thawed fish or fillets. Journal of the Science of Food and Agriculture, 82: 1341-1345.
Go to original source...
- Dufour E., Frencia J.P., Kane E. (2003): Development of a rapid method based on front-face fluorescence spectroscopy for the monitoring of fish freshness. Food Research International, 36: 415-423.
Go to original source...
- Dufour E., Letort A., Laguet A., Lebecque A., Serra J.N. (2006): Investigation of variety, typicality and vintage of French and German wines using front-face fluorescence spectroscopy. Analytica Chimica Acta, 563: 292-299.
Go to original source...
- Egelandsdal B., Wold J.P., Sponnich A., Neegård S., Hildrum K.I. (2002): On attempts to measure the tenderness of Longissimus Dorsi muscles using fluorescence emission spectra. Meat Science, 60: 187-202.
Go to original source...
Go to PubMed...
- Eisinger J., Flores J. (1979): Front-face fluorometry of liquid samples. Analytical Biochemistry, 94: 15-21.
Go to original source...
Go to PubMed...
- Geladi P. (2003): Chemometrics in spectroscopy. Part I. Classical chemometrics. Spectrochimica Acta Part B, 58: 767-782.
Go to original source...
- Genot C., Tonetti F., Montenay-Garestier T., Marion D., Drapon R. (1992a): Front-face fluorescence applied to structural studies of proteins and lipid-protein interactions of visco-elastic food products. 1-Designing of front-face adaptor and validity of front-face fluorescence measurements. Sciences des Aliments, 12: 199-212.
- Genot C., Tonetti F., Montenay-Garestier T., Marion D., Drapon R. (1992b): Front-face fluorescence applied to structural studies of proteins and lipidprotein interactions of visco-elastic food products. 2-Application to wheat gluten. Sciences des Aliments, 12: 687-704.
- Guimet F., Ferré J., Boqué R., Rius F.X. (2004): Application of unfold principal component analysis and parallel factor analysis to the exploratory analysis of olive oils by means of excitation emission matrix fluorescence spectroscopy. Analytica Chimica Acta, 515: 75-85.
Go to original source...
- Guimet F., Ferré J., Boqué R. (2005): Rapid detection of olive-pomace oil adulteration in extra virgin olive oils from the protected denomination of origin "Siurana" using excitation-emission fluorescence spectroscopy and three-way methods of analysis. Analytica Chimica Acta, 544: 143-152.
Go to original source...
- Guimet F., Boqué R., Ferré J. (2006): Application of non-negative matrix factorization combined with Fisher's linear discriminant analysis for classification of olive oil excitation emission fluorescence spectra. Chemometrics and Intelligent Laboratory Systems, 81: 94-106.
Go to original source...
- Herbert S., Riou N.M., Devaux M.F., Riaublan A., Bouchet B., Galllant D.J., Dufour E. (2000): Monitoring the identity and the structure of soft cheese by fluorescence spectroscopy. Le Lait, 80: 621-634.
Go to original source...
- Hirsch R.E., Nagel R.L. (1989): Stopped-flow front-face fluorometer: A prototype design to measure hemoglobin R → T transition kinetics. Analytical Biochemistry, 176: 19-21.
Go to original source...
Go to PubMed...
- Hirschfeld T. (1978): Comparison of inner filter effects in "front face" and total reflection fluorescence. Spectrochimica Acta Part A: Molecular Spectroscopy, 34: 693-694.
Go to original source...
- Jensen S.A, Reenberg S., Munck L. (1986): U.S. Patent US4631413.
- Jensen P.N., Christensen J., Engelsen S.B. (2004): Oxidative changes in pork scratchings, peanuts, oatmeal and muesli viewed by fluorescence, near-infrared and infrared spectroscopy. European Food Research and Technology, 219: 294-304.
Go to original source...
- Karoui R., Dufour E. (2003): Dynamic testing rheology and fluorescence spectroscopy investigations of surface to centre differences in ripened soft cheeses. International Dairy Journal, 13: 973-985.
Go to original source...
- Karoui R., Dufour E. (2006): Prediction of the rheology parameters of ripened semi-hard cheeses using fluorescence spectra in the UV and visible ranges recorded at a young stage. International. Dairy Journal, 16: 1490-1497.
Go to original source...
- Karoui R., Mazerolles G., Dufour E. (2003): Spectroscopic techniques coupled with chemometric tools for structure and texture determinations in dairy products. International Dairy Journal, 13: 607-620.
Go to original source...
- Karoui R., Dufour E., Pillonel L., Schaller E., Picque D., Cattenoz T., Bosset J.O. (2004): Determining the geographic origin of Emmental cheeses produced during winter and summer using a technique based on the concatenation of MIR and fluorescence spectroscopic data. European Food Research and Technology, 219: 184-189.
Go to original source...
- Karoui R., Dufour E., Pillonel L., Schaller E., Picque D., Cattenoz T., Bosset J.O. (2005a): The potential of combined infrared and fluorescence spectroscopies as a method of determination of the geographic origin of Emmental cheeses. International Dairy Journal, 15: 287-298.
Go to original source...
- Karoui R., Bosset J.O., Mazerolles G., Kulmyrzaev A., Dufour E. (2005b): Monitoring the geographic origin of both experimental French Jura hard cheeses and Swiss Gruyère and L'Etivaz PDO cheeses using mid-infrared and fluorescence spectroscopies: a preliminary investigation. International Dairy Journal, 15: 275-286.
Go to original source...
- Karoui R., Dufour E., De Baerdemaeker J. (2006a): Common components and specific weights analysis: A tool for monitoring the molecular structure of semihard cheese throughout ripening. Analytica Chimica Acta, 572: 125-133.
Go to original source...
Go to PubMed...
- Karoui R., Kemps B., Bamelis F., De Ketelaere B., Decuypere E., De Baerdemaeker J. (2006b): Methods to evaluate egg freshness in research and industry: A review. European Food Research and Technology, 222: 727-732.
Go to original source...
- Karoui R., Kemps B., Bamelis F., De Ketelaere B., Decuypere E., De Baerdemaeker J. (2006c): Development of a rapid method based on front face fluorescence spectroscopy for the monitoring of egg freshness: 1-evolution of thick and thin egg albumens. European Food Research and Technology, 223: 303-312.
Go to original source...
- Karoui R., Kemps B., Bamelis F., De Ketelaere B., Merten K., Schoonheydt R., Decuypere E., De Baerdemaeker J. (2006d): Development of a rapid method based on front-face fluorescence spectroscopy for the monitoring of egg freshness: 2-evolution of egg yolk. European Food Research and Technology, 223: 180-188.
Go to original source...
- Karoui R., Thomas E., Dufour E. (2006e): Utilisation of a rapid technique based on front-face fluorescence spectroscopy for differentiating between fresh and frozen-thawed fish fillets. Food Research International, 39: 349-355.
Go to original source...
- Karoui R., Dufour E., Schoonheydt R., De Baerdemaeker J. (2007a): Characterisation of soft cheese by front face fluorescence spectroscopy coupled with chemometric tools: Effect of the manufacturing process and sampling zone. Food Chemistry, 100: 632-642.
Go to original source...
- Karoui R., Dufour E., De Baerdemaeker J. (2007b): Front face fluorescence spectroscopy coupled with chemometric tools for monitoring the oxidation of semi-hard cheeses throughout ripening. Food Chemistry, 101: 1305-1314.
Go to original source...
- Karoui R., Dufour E., Bosset J.O., De Baerdemaeker J. (2007c): The use of front face fluorescence spectroscopy to classify the botanical origin of honey samples produced in Switzerland. Food Chemistry, 101: 314-323.
Go to original source...
- Kulmyrzaev A., Dufour E., Noël Y., Hanafi M., Karoui R., Qannari E.M., Mazerolles G. (2005): Investigation at the molecular level of soft cheese quality and ripening by infrared and fluorescence spectroscopies and chemometrics relationships with rheology properties. International Dairy Journal, 15: 669-678.
Go to original source...
- Kyriakidis N.B., Skarkalis P. (2000): Fluorescence spectra measurement of olive oil and other vegetable oils. Journal of AOAC International, 83: 1435-1439.
Go to original source...
Go to PubMed...
- Mas P.A., Bouveresse D.J.R., Birlouez-Aragon I. (2004): Fluorescence spectroscopy for monitoring repaseed oil upon heating. Czech Journal of Food Sciences, 22: 127-129.
Go to original source...
- Mazerolles G., Devaux M.F., Dufour E., Qannari E.M. (2002): Chemometric methods for the coupling of spectroscopic techniques and for the extraction of the relevant information contained in the spectral data tables. Chemometrics and Intelligent Laboratory Systems, 63: 57-68.
Go to original source...
- Mazerolles G., Hanafi M., Dufour E., Bertrand D., Qannari E.M. (2006): Common components and specific weights analysis: A chemometric method for dealing with complexity of food products. Chemometrics and Intelligent Laboratory Systems, 81: 41-49.
Go to original source...
- Miquel Becker E., Christensen J., Frederiksen C.S., Haugaard V.K. (2003): Front-face spectroscopy and chemometrics in analysis of yogurt: rapid analysis of riboflavin. Journal of Dairy Science, 86: 2508-2515.
Go to original source...
Go to PubMed...
- Møller J.K.S., Parolari G., Gabba L., Christensen J., Skibsted L.H. (2003): Monitoring chemical changes of dry-cured Parma ham during processing by surface autofluorescence spectroscopy. Journal of Agricultural and Food Chemistry, 51: 1224-1230.
Go to original source...
Go to PubMed...
- Moon S.K., Yud-Ren CH., Sukwon K., Intaek K., Lefcourt A.M., Moonjohn K. (2006): Fluorescence characteristics of wholesome and unwholesome chicken carcasses. Applied Spectroscopy, 60: 1210-1211.
Go to original source...
Go to PubMed...
- Munck L., Norgaard L., Engelsen S.B., Bro R., Andersson C.A. (1998): Chemometrics in food science - a demonstration of the feasibility of a highly exploratory, inductive evaluation strategy of fundamental scientific significance. Chemometrics and Intelligent Laboratory Systems, 44: 31-60.
Go to original source...
- Norgaard L. (1995): A multivariate chemometric approach to fluorescence spectroscopy. Talanta, 42: 1305-1324.
Go to original source...
Go to PubMed...
- Parker C.A. (1968): Photoluminescence of solutions with applications to photochemistry and analytical chemistry. In: Parker C.A (ed.): Apparatus and Experimental Methods. Elsevier: 128-302.
- Patra D., Mishra A.K. (2002): Recent developments in multi-component synchronous fluorescence scan analysis. Trends in Analytical Chemistry, 21: 787-798.
Go to original source...
- Poulli K.I., Mousdis G.A., Georgiou C.A. (2005): Classification of edible and lampante virgin olive oil based on synchronous fluorescence and total luminescence spectroscopy. Analytica Chimica Acta, 542: 151-156.
Go to original source...
- Ruoff K., Karoui R., Dufour E., Luginbühl W., Bosset J.O., Bogdanov S. (2005): Authentication of the botanical origin of honey by front-face fluorescence spectroscopy, a preliminary study. Journal of Agricultural and Food Chemistry, 53: 1343-1347.
Go to original source...
Go to PubMed...
- Sayago A., Morales M.T., Aparicio R. (2004): Detection of hazelnut oil in virgin olive oil by a spectrofluorimetric method. European Food Research and Technology, 218: 480-483.
Go to original source...
- Sikorska E., Górecki T., Khmelinskii I.V., Sikorski M., Kozio J. (2005): Classification of edible oils using synchronous scanning fluorescence spectroscopy. Food Chemistry, 89: 217-225.
Go to original source...
- Sikorska E., Górecki T., Khmelinskii I.V., Sikorski M., De Keukeleire D. (2006): Monitoring beer during storage by fluorescence spectroscopy. Food Chemistry, 96: 632-639.
Go to original source...
- Sóti R., Farkas É., Hilbert M., Farkas Zs., Ketskeméty I. (1993): Theoretical treatment of reabsorption in luminescent layers. Journal of Luminescence, 55: 5-10.
Go to original source...
- Swatland H.J. (1987): Autofluorescence of adipose tissue measured with fibre optics. Meat Science, 19: 277-284.
Go to original source...
Go to PubMed...
- Swatland H.J. (1994): Physical measurements of meat quality: optical measurements, pros and cons. Meat Science, 36: 251-259.
Go to original source...
Go to PubMed...
- Swatland H.J. (2000): Connective and adipose tissue detection by simultaneous fluorescence and reflectance measurements with an on-line meat probe. Food Research International, 33: 749-757.
Go to original source...
- Swatland H.J. (2001): A note on the stereological anatomy of four probe sites in beef carcasses. Food Research International, 34: 633-637.
Go to original source...
- Veberg A., Vogt G., Wold J.P. (2006): Fluorescence in aldehyde model systems related to lipid oxidation. LWT - Food Science and Technology, 39: 562-568.
Go to original source...
- Wold J.P., Jørgensen K., Lundby F. (2002): Nondestructive measurement of light-induced oxidation in dairy products by fluorescence spectroscopy and imaging. Journal of Dairy Science, 85: 1693-1704.
Go to original source...
Go to PubMed...
This is an open access article distributed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International (CC BY NC 4.0), which permits non-comercial use, distribution, and reproduction in any medium, provided the original publication is properly cited. No use, distribution or reproduction is permitted which does not comply with these terms.