Czech J. Food Sci., 2023, 41(1):54-63 | DOI: 10.17221/155/2022-CJFS
Influence of the surface/volume ratio on the rheological properties of starch dispersionsOriginal Paper
- 1 Instituto Politécnico Nacional, CICATA-IPN Querétaro, Santiago de Querétaro, Querétaro, México
- 2 Department of Nuclear Engineering, The Pennsylvania State University, Pennsylvania, USA
This study aims to evaluate the influence of the surface/volume granule ratio of amaranth, corn, and potato starches on the rheological properties of pastes and gels obtained at 5 and 10% solids concentration through granulometry, scanning electron microscopy, rotational, and dynamic rheological measurements. The granule size distribution and the surface/volume ratio drove the rheological behaviour as a function of temperature and concentration. At a concentration of 10%, the consistency index of corn starch (CS) paste was 147.25 Pa·sn (n – flow behavior index), a higher value compared to pastes from potato starch (PS), 86.54 Pa·sn, and amaranth starch (AS), 44.48 Pa·sn. The lowest values of the loss angle tangent (Tan δ) in CS (0.052 and 0.035) at both solids concentrations suggested a better gel conformation. Noticeable changes in consistency index and storage modulus were observed in CS. A theoretical analysis of the surface/volume ratio change showed that CS reached a 2.2 value, much lower than the 4.5 and 5.8 values for PS and AS, respectively. These findings provide additional criteria for the food industry when choosing starches with suitable rheological behaviour as a function of surface/volume granule ratio and solids concentration.
Keywords: granulometry; Pasting properties; polymer gels; rheology; solids concentration
Accepted: February 23, 2023; Prepublished online: February 24, 2023; Published: February 27, 2023 Show citation
| ACS | AIP | APA | ASA | Harvard | Chicago | Chicago Notes | IEEE | ISO690 | MLA | NLM | Turabian | Vancouver |
References
- Cabrera-Ramirez A.H., Castro-Campos F.G., Gaytan-Martinez M., Morales-Sanchez E. (2020): Relationship between the corneous and floury endosperm content and the popped sorghum quality. Journal of Cereal Science, 95: 102999.
Go to original source... - Doublier J.L., Llamas G., Le Meur M. (1987): A rheological investigation of cereal starch pastes and gels. Effect of pasting procedures. Carbohydrate Polymers, 7: 251-275.
Go to original source... - Fonseca-Florido H.A., Méndez-Montealvo G., Velazquez G., Gómez-Aldapa C.A. (2016): Thermal study in the interactions of starches blends: Amaranth and achira. Food Hydrocolloids, 61: 640-648.
Go to original source... - Fonseca-Florido H.A., Castro-Rosas J., Hernández-Hernández E., Mata-Padilla J.M., Velazquez G., Ávila-Orta C.A., Rodríguez-Hernández A.I., Gomez-Aldapa C.A. (2017): Structural properties of the waxy corn and potato starch blends in excess water. International Journal of Food Properties, 20: S353-S365.
Go to original source... - Genovese D.B., Rao M.A. (2003): Role of starch granule characteristics (volume fraction, rigidity, and fractal dimension) on rheology of starch dispersions with and without amylose. Cereal Chemistry, 80: 350-355.
Go to original source... - González-Reyes E., Méndez-Montealvo G., Solorza-Feria J., Toro-Vazquez J.F., Bello-Pérez L.A. (2003): Rheological and thermal characterization of Okenia hypogaea (Schlech. & Cham.) starch. Carbohydrate Polymers, 52: 297-310.
Go to original source... - Herrera-Gómez A., Canónico-Franco M., Ramos G. (2005): Aggregate formation and segregation of maize starch granules cooked at reduced moisture conditions. Starch - Stärke, 57: 301-309.
Go to original source... - Kong X., Bao J., Corke H. (2009): Physical properties of Amaranthus starch. Food Chemistry, 113: 371-376.
Go to original source... - Lagarrigue S., Alvarez G. (2001): The rheology of starch dispersions at high temperatures and high shear rates: A review. Journal of Food Engineering, 50: 189-202.
Go to original source... - Matignon A., Tecante A. (2017): Starch retrogradation: From starch components to cereal products. Food Hydrocolloids, 68: 43-52.
Go to original source... - Okechukwu P.E., Rao M.A. (1996): Role of granule size and size distribution in the viscosity of cowpea starch dispersions heated in excess water. Journal of Texture Studies, 27: 159-173.
Go to original source... - Rao M.A., Okecbukwu P.E., Da Silva P.M.S., Oliveirab J.C. (1997): Rheological behavior of heated starch dispersions in excess water: Role of starch granule. Carbohydrate Polymers, 33: 273-283.
Go to original source... - Romesburg H.C. (2011): Pedagogical positives of the surface-to-volume ratio. American Biology Teacher, 73: 260-264.
Go to original source... - Singh N., Singh J., Kaur L., Sodhi N.S., Gill B.S. (2003): Morphological, thermal and rheological properties of starches from different botanical sources. Food Chemistry, 81: 219-231.
Go to original source... - Singh N., Kaur L. (2004): Morphological, thermal, rheological and retrogradation properties of potato starch fractions varying in granule size. Journal of the Science of Food and Agriculture, 84: 1241-1252.
Go to original source... - Steffe J.F. (1996): Rheological Methods in Food Process Engineering. Freeman Press.East Lansing, Freeman Press: 428.
- Tecante A. (2001): Viscoelasticity. In: Encyclopedia of Life Support Systems (EOLSS), Oxford, UNESCO, Eolss Publishers: 292-304.
- Tester R.F., Karkalas J., Qi X. (2004): Starch - composition, fine structure and architecture. Journal of Cereal Science, 39: 151-165.
Go to original source... - Vamadevan V., Bertoft E. (2015): Structure-function relationships of starch components. Starch - Stärke, 67: 55-68.
Go to original source... - Wang L., Wang Y.J. (2004): Rice starch isolation by neutral protease and high-intensity ultrasound. Journal of Cereal Science, 39: 291-296.
Go to original source... - Wang X., Lui S., Ai Y. (2022): Gelation mechanisms of granular and non-granular starches with variations in molecular structures. Food Hydrocolloids, 129: 107658.
Go to original source... - Waterschoot J., Gomand S.V., Delcour J.A. (2016): Impact of swelling power and granule size on pasting of blends of potato, waxy rice and maize starches. Food Hydrocolloids, 52: 69-77.
Go to original source...
This is an open access article distributed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International (CC BY NC 4.0), which permits non-comercial use, distribution, and reproduction in any medium, provided the original publication is properly cited. No use, distribution or reproduction is permitted which does not comply with these terms.

