Czech J. Food Sci., 2012, 30(2):171-175 | DOI: 10.17221/57/2011-CJFS
Effect of temperature on the antioxidant activity of phenolic acids
- Department of Food Chemistry and Analysis, Faculty of Food and Biochemical Technology, Institute of Chemical Technology Prague, Prague, Czech Republic
The effect of temperature on the antioxidant activity of phenolic acids (gallic, gentisic, protocatechuic, syringic, vanillic, ferulic, caffeic, and sinapic; 0.5 mmol/kg) was studied in pork lard, using an Oxipres apparatus, at a temperature range of 90°C to 150°C. The antioxidant activity of all studied compounds decreased with increasing working temperature, whereas a linear relationship (P < 0.01) existed between temperature and the antioxidant activity in all cases. However, the relative rate of the antioxidant activity decrease with increasing temperature (i.e. in comparison with the activity at 90°C) was not the same for all studied phenolic acids. Easily oxidisable phenolic acids (i.e. gallic, gentisic, protocatechuic, and caffeic) showed a slower decrease in antioxidant activity with increasing temperature (in comparison with their activity at 90°C) than the less oxidisable ones (i.e. syringic, ferulic and sinapic acids, and especially vanillic acid). Consequently, only gallic, gentisic, protocatechuic, and caffeic acids showed a significant antioxidant activity at 150°C and vanillic acid was active only at 90°C.
Keywords: antioxidants; pork lard; oxidasability; Oxipres
Published: April 30, 2012 Show citation
References
- Amorati R., Pedulli G.F., Cabrini L., Zambonin L., Landi L. (2006): Solvent and pH effects on the antioxidant activity of caffeic and other phenolic acids. Journal of Agricultural and Food Chemistry, 54: 2932-2937.
Go to original source...
Go to PubMed...
- Armando C., Maythe S., Beatriz N.P. (1998): Antioxidant activity of grapefruit seed extract on vegetable oils. Journal of the Science of Food and Agriculture, 77: 463-467.
Go to original source...
- Becker E.M., Nissen L.R., Skibsted L.H. (2004): Antioxidant evaluation protocols: food quality or health effects. European Food Research and Technology, 219: 561-571.
Go to original source...
- Cho H.-Y. (1997): Reaction mechanisms and kinetics of antioxidant using Arrhenius equation in soybean oil oxidation. Journal of Food Science and Nutrition, 2: 6-10.
- Choe E., Min D.B. (2009): Mechanisms of antioxidants in the oxidation of foods. Comprehensive Reviews in Food Science and Food Safety, 8: 345-358.
Go to original source...
- Evans J.C., Kodali D.R., Addis P.B. (2002): Optimal tocopherol concentrations to inhibit soybean oil oxidation. Journal of the American Oil Chemists' Society, 79: 47-51.
Go to original source...
- Frankel E.N. (1980): Lipid oxidation. Progress in Lipid Research, 19: 1-22.
Go to original source...
Go to PubMed...
- Frankel E.N. (1996): Antioxidants in lipid foods and their impact on food quality. Food Chemistry, 57: 51-55.
Go to original source...
- Karadag A., Ozcelik B., Saner S. (2009): Review of methods to determine antioxidant capacities. Food Analytical Methods, 2: 41-60.
Go to original source...
- Kolb T., Loyall U., Schäfer J. (2002): Antioxidants. determination and interpretation of the temperature correlation of oxidative stabilities. Food Marketing & Technology, 16: 27-32.
- Lomanno S.S., Navar W.W. (1982): Effect of heating temperature and time on the volatile oxidative decomposition of linolenate. Journal of Food Science, 47: 744-746.
Go to original source...
- Marinova E.M., Yanishlieva N.V. (1992): Effect of temperature on the antioxidative action of inhibitors in lipid autoxidation. Journal of the Science of Food and Agriculture, 60: 313-318.
Go to original source...
- Marinova E.M., Yanishlieva N.V. (1996): Antioxidative action of some flavonoids at ambient and high temperatures. Rivista Italiana delle Sostanze Grasse, 73: 445-449.
- Marinova E.M., Yanishlieva N.V. (1998): Antioxidative action of quercetin and morin in triacylglycerols of sunflower oil at ambient and high temperatures. Seifen Öle Fette Wachse, 124: 10-16.
- Marinova E.M., Yanishlieva N.V. (2003): Antioxidant activity and mechanism of action of some phenolic acids at ambient and high temperatures. Food Chemistry, 81: 189-197.
Go to original source...
- Nakatani N., Tachibana Y., Kikuzaki H. (2001): Establishment of a model substrate oil for antioxidant activity assessment by oil stability index method. Journal of the American Oil Chemists' Society, 78: 19-23.
Go to original source...
- Pokorný J. (1986): Addition of antioxidants for food stabilization to control oxidative rancidity. Czech Journal of Food Sciences, 4: 299-307.
- Réblová Z. (2006): The effect of temperature on the antioxidant activity of tocopherols. European Journal of Lipid Science and Technology, 108: 858-863.
Go to original source...
- Reynhout G. (1991): The effect of temperature on the induction time of a stabilized oil. Journal of the American Oil Chemists' Society, 68: 983-984.
Go to original source...
- Trojáková L., Réblová Z., Pokorný J. (1999): Determination of the oxidative stability of fats and oils using the Oxipres apparatus. Czech Journal of Food Sciences, 17: 68-72.
- Verleyen T., Kamal-Eldin A., Mozuraityte R., Verhé R., Dewettinck K., Huyghebaert A., de Grey W. (2002): Oxidation at elevated temperatures: competition between α-tocopherol and unsaturated triacylglycerols. European Journal of Lipid Science and Technology, 104: 228-233.
Go to original source...
- Wagner K.-H., Wotruba F., Elmadfa I. (2001): Antioxidative potential of tocotrienols and tocopherols in coconut fat at different oxidation temperatures. European Journal of Lipid Science and Technology, 103: 746-751.
Go to original source...
- Yanishlieva N.V. (2001): Inhibiting oxidation. In: Pokorný J., Yanishlieva N.V., Gordon H. (eds): Antioxidants in Food - Practical Applications. Woodhead Publishing, Cambridge: 22-70.
Go to original source...
- Yanishlieva N.V., Marinova E.M. (1996): Antioxidative effectiveness of some natural antioxidants in sunflower oil. Zeitschrift für Lebensmittel-Untersuchung und Forschung, 203: 220-223.
Go to original source...
Go to PubMed...
- Zandi P., Ahmadi L. (2000): Antioxidant effect of plant extracts of Labiatae family. Journal of Lipid Science and Technology, 37: 436-439.
- Zhang C.X., Wu H., Weng X.C. (2004): Two novel synthetic antioxidants for deep frying oils. Food Chemistry, 84: 219-222.
Go to original source...
This is an open access article distributed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International (CC BY NC 4.0), which permits non-comercial use, distribution, and reproduction in any medium, provided the original publication is properly cited. No use, distribution or reproduction is permitted which does not comply with these terms.