Czech J. Food Sci., 2012, 30(1):67-73 | DOI: 10.17221/329/2010-CJFS
Methodology development for routine estimation of chlorpropham in commercial potato stores
- 1 Food, Agriculture and Environmental Chemistry and 3Department of Chemistry, University of Glasgow, Glasgow, UK
- 2 Department of Food Science and Technology, Gomal University, Dera Ismail Khan, Pakistan
Chlorpropham is employed worldwide as an anti-sprout chemical to the harvested potato tubers during storage. A simple and precise analytical technique is developed for routine estimation of the sprout suppressant from a large number of potato samples supplied from commercial stores demanding quick analysis. Chlorpropham is extracted completely from potato tubers by intelligent reflux extraction followed by quantification using GC-FID (Gas Chromatography-Flame Ionization Detector) equipment. In this article, the performance of the technique is compared with the lengthy extraction/cleanup process, and the results are validated as per one-way analysis of variance. The recommended technique is found to offer rapid, accurate, and reliable analytical results with ease in handling a large number of samples constituting a wide range of residual chlorpropham levels often found in a complex structural commercial potato stores.
Keywords: chlorpropham; sprout suppressant; anti-sprout; soxhlet extraction; potato
Published: February 29, 2012 Show citation
References
- Ascenzo G., Gentili A., Marchese S., Mariono A., Perret D. (1998): Multiresidue method for determination of post-emergence herbicides in water by HPLC/ESI/MS in positive ionization mode. Environmental Science and Technology, 32: 1340-1347.
Go to original source... - Batora V., Vitorovic S.L.J., Their H.P., Klisenko M.A. (1981): Development and evaluation of simplified approaches to residue analysis. Pure and Applied Chemistry, 53: 1039-1049.
Go to original source... - Beernert H., Hucorne P. (1991): A simple and quick gas chromatographic method for the determination of propham and chlorpropham in potatoes. Zeitschrift für Lebensmittel-Untersuchung und -Forschung, 193: 433-435.
Go to original source...
Go to PubMed... - Boyd I.M.G. (1988): Studies on the potato sprout suppressant chlorpropham. [Thesis.] University of Glasgow.
- Chen Guoqiang, Pengying C., Liu Renjiang (2010): A multi-residue method for fast determination of pesticides in tea by ultra performance liquid chromatography-electrospray tandem mass spectrometry combined with modified QuEChERS sample preparation procedure. Food Chemistry, 125: 1406-1411.
Go to original source... - Corsini D., Stalknecht G., Sparks W. (1978): A simplified method for determining sprout-inhibiting levels of chlorpropham (CIPC) in potatoes. Journal of Agricultural and Food Chemistry, 26: 990-991.
Go to original source...
Go to PubMed... - Heras A.P., Sanchez R. (1982): Determination of carbamic herbicides by high performance liquid chromatography (HPLC). II. Chlorpropham. Journal of Liquid Chromatography, 5: 327-335.
Go to original source... - Kadamne J., Proctor A. (2010): Rapid oil extraction from potato chips. Journal of American Oil Chemists' Society, 87: 835-836.
Go to original source... - Kerstholt R.P.V., Ree C.M., Moll H.C. (1997): Environmental life cycle analysis of potato sprout inhibitors. Industrial Crops and Products, 6: 187-194.
Go to original source... - Lewis D. J., Thorpe S.A., Reynolds S.L. (1996): The carry-through of residues of thiabendazole, tecnazene and chlorpropham from potatoes following manufacture into potato crisps and jacket potato crisps. Food Additives and Contaminants, 13: 221-229.
Go to original source...
Go to PubMed... - Nakagawa H., Lockman J.C., Frankel W.L., Hampel H., Steenblock K., Burgart I.J., Thibodeau S.N., de la Chapelle A. (2004). Mismatch repair gene PMS2: disease-causing germline mutations are frequent in patients whose tumors stain negative for PMS2 protein, but paralogous genes obscure mutation detection and interpretation. Cancer Research, 64: 4721-4727.
Go to original source...
Go to PubMed... - Ritchie W., Boyed I.M.G., Duncan H.J. (1983): Method for the determination of chloro residues in crisps and crisps frying oil. Potato Research, 26: 73-77.
Go to original source... - Vliet V.W.F., Hertog S. (1966): The analysis of sprout inhibitor residues in the potato tuber. European Potato Journal, 9:152-160.
Go to original source...
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