Czech J. Food Sci., 2008, 26(5):360-367 | DOI: 10.17221/1125-CJFS

Nondestructive identification of tea (Camellia sinensis L.) varieties using FT-NIR spectroscopy and pattern recognition

Quansheng Chen1, Jiewen Zhao1, Muhua Liu2, Jianrong Cai1
1 School of Food & Biological Engineering, Jiangsu University, Zhenjiang, P. R. China
2 Engineering College, Jiangxi Agricultural University, Nanchang, P. R. China

Due to more and more tea varieties in the current tea market, rapid and accurate identification of tea (Camellia sinensis L.) varieties is crucial to the tea quality control. Fourier Transform Near-Infrared (FT-NIR) spectroscopy coupled with the pattern recognition was used to identify individual tea varieties as a rapid and non-invasive analytical tool in this work. Seven varieties of Chinese tea were studied in the experiment. Linear Discriminant Analysis (LDA) and Artificial Neural Network (ANN) were compared to construct the identification models based on Principal Component Analysis (PCA). The number of principal components factors (PCs) was optimised in the constructing model. The experimental results showed that the performance of ANN model was better than LDA models. The optimal ANN model was achieved when four PCs were used, identification rates being all 100% in the training and prediction sets. The overall results demonstrated that FT-NIR spectroscopy technology with ANN pattern recognition method can be successfully applied as a rapid method to identify tea varieties.

Keywords: green tea; variety; identification; FT-NIR spectroscopy; pattern recognition

Published: October 31, 2008  Show citation

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Chen Q, Zhao J, Liu M, Cai J. Nondestructive identification of tea (Camellia sinensis L.) varieties using FT-NIR spectroscopy and pattern recognition. Czech J. Food Sci. 2008;26(5):360-367. doi: 10.17221/1125-CJFS.
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References

  1. Blanco M., Coello J., Iturriaga H., Maspoch S., Pagès J. (1999): Calibration in non-linear near infrared reflectance spectroscopy: a comparison of several methods. Analytica Chimica Acta, 384: 207-214. Go to original source...
  2. Chen Q.S., Zhao J.W., Huang X.Y., Zhang H.D., Liu M.H. (2006a): Simultaneous determination of total polyphenols and caffeine contents of green tea by near-infrared reflectance spectroscopy. Microchemical Journal, 83: 42-47. Go to original source...
  3. Chen Q.S., Zhao J.W., Zhang H.D., Wang X.Y. (2006b): Feasibility study on qualitative and quantitative analysis in tea by near infrared spectroscopy with multivariate calibration. Analytica Chimica Acta, 572: 77-84. Go to original source... Go to PubMed...
  4. Chen Q.S., Zhao J.W., Cai J.R. (2008): Identification of tea varieties using computer vision. Transcations of ASABE, 51: 623-628. Go to original source...
  5. Clark C.J., Mcglone V.A., Jordan R.B. (2005): Detection of Brownheart in 'Braeburn' apple by transmission NIR spectroscopy. Postharvest Biology and Technology, 28: 65-71. Go to original source...
  6. Esteban-Diez I., Gonzalez-Saiz J.M., Pizarro C. (2004): An evaluation of orthogonal signal correction methods for the characterization of Arabica and Robusta coffee varieties by NIRS. Analytica Chimica Acta, 514: 57-67. Go to original source...
  7. Hall M.N., Robertson A., Scotter C.N.G. (1988): Near-infrared reflectance prediction of quality, theaflavin content and moisture content of black tea. Food Chemistry, 27: 61-75. Go to original source...
  8. Herrador M.A., Gonzalez A.G. (2001): Pattern recognition procedures for differentiation of green, black and Oolong teas according to their metal content from inductively coupled plasma atomic emission spectrometry. Talanta, 53: 1249-1257. Go to original source... Go to PubMed...
  9. Hideki H., Toshihiro M., Katsunori K. (1997): Simultaneous determination of qualitatively important components in green tea infusions using capillary electrophoresis. Journal of Chromatography A, 758: 332-335. Go to original source...
  10. Huck C.W., Guggenbichler W., Bonn G.K. (2005): Analysis of caffeine, theobromine and theophylline in coffee by near infrared spectroscopy compared to high-performance liquid chromatography (HPLC) coupled to mass spectrometry. Journal of Pharmaceutical Biomedical Analysis, 538: 195-203. Go to original source...
  11. Luo Y.F., Guo Z.F., Zhu Z.Y., Wang C.P., Jiang H.Y., Han B.Y. (2005): Studies on ANN models of determination of tea polyphenol and amylose in tea by near-infrared spectroscopy. Spectroscopy Spectral Analysis, 25: 1230-1233.
  12. Luypaert J., Zhang M.H., Massart D.L. (2003): Feasibility study for the using near infrared spectroscopy in the qualitative and quantitative of green tea, Camellia sinensis (L). Analytica Chimica Acta, 487: 303-312. Go to original source...
  13. McGlone V.A., Jordan R.B., Seelye R., Martinsen P.J. (2002): Comparing density and NIR methods for measurement of kiwi fruit dry matter and soluble solids content. Postharvest Biology and Technology, 26: 191-198. Go to original source...
  14. Mouwen D.J.M., Capita R., Alonso-Calleja C., Prieto-Gómez J., Prieto M. (2006): Artificial neural network based identification of Campylobacter species by Fourier transform infrared spectroscopy. Journal of Microbiological Methods, 67: 131-140. Go to original source... Go to PubMed...
  15. Roggo Y., Duponchel L., Huvenne J.P. (2003): Comparison of supervised pattern recognition methods with McNemar's statistical test. Application to qualitative analysis of sugar beet by near-infrared spectroscopy. Analytica Chimica Acta, 477: 187-200. Go to original source...
  16. Schulz H., Engelhardt U.H., Wegent A., Drews H.H., Lapczynski S. (1999): Application of NIRS to the simultaneous prediction of alkaloids and phenolic substances in green tea leaves. Journal of Agricultural and Food Chemistry, 475: 5064-5067. Go to original source... Go to PubMed...
  17. Sun Y.G., Lin M., Lv J., Xu L.H. (2004): Determination of the contents of free amino acids, caffeine and tea polyphenols in green tea by Fourier transform nearinfrared spectroscopy. Chinese Journal of Spectroscopy Laboratory, 21: 940-943.
  18. Togari N., Kobayashi A., Aishima T. (1995): Pattern recognition applied to gas chromatographic profiles of volatile component in three tea categories. Food Research International, 28: 495-502. Go to original source...
  19. Valera P., Pablo F., Gonzalez A.G. (1996): Classification of tea samples by their chemical composition using discriminant analysis. Talanta, 43: 415-419. Go to original source... Go to PubMed...
  20. Woo Y.A., Kim H.J., Ze K.R., Chung H. (2005): Nearinfrared (NIR) spectroscopy for the non-destructive and fast determination of geographical origin of Angelicae gigantis Radix. Journal of Pharmaceutical Biomedical Analysis, 36: 955-959. Go to original source... Go to PubMed...
  21. Yan S.H. (2005): Evaluation of the composition and sensory properties of tea using near infrared spectroscopy and principal component analysis. Journal Near Infrared Spectroscopy, 6: 313-325. Go to original source...
  22. Yang H., Irudayaraj J., Paradkar M.M. (2005): Discriminant analysis of edible oils and fats by FTIR, FT-NIR and FT-Raman spectroscopy. Food Chemistry, 93: 25-32. Go to original source...
  23. Zhang M.H., Luypaert J., Xu Q.S., Massart D.L. (2004): Determination of total antioxidant capacity in green tea by NIRS and multivariate calibration. Talanta, 62: 25-35. Go to original source... Go to PubMed...
  24. Zhao J.W., Chen Q.S., Huang X.Y., Fang C.H. (2006): Qualitative identification of tea categories by near infrared spectroscopy and support vector machine. Journal of Pharmaceutical Biomedical Analysis, 41: 1198-1204. Go to original source... Go to PubMed...
  25. Zuo Y.G., Chen H., Deng Y.W. (2002): Simultaneous determination of catechins, caffeine and gallic acids in green, Oolong, black and pu-erh teas using HPLC with a photodiode array detector. Talanta, 57: 307-316. Go to original source... Go to PubMed...

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