Czech J. Food Sci., 2007, 25(5):257-264 | DOI: 10.17221/679-CJFS

Analysis of the lipid fractions of coffee creamers, cream aerosols, and bouillon cubes for their health risk associated constituents

Lenka Karšulínová, Blanka Folprechtová, Marek Doležal, Jana Dostálová, Jan Velíšek
Department of Food Chemistry and Analysis, Faculty of Food and Biochemical Technology, Institute of Chemical Technology in Prague, Prague, Czech Republic

Fifteen coffee creamers, 10 cream aerosols, and 5 bouillon cubes from the retail market were analysed, principally for their contents of trans-fatty acids that are known to increase the risk of coronary heart disease, and for their contents of 3-chloropropane-1,2-diol (3-MCPD) fatty acid esters that possibly have a bioaccumulation potential. The contents of trans-fatty acids in coffee creamers, cream aerosols and bouillon cubes were in the range of 0.2-32.8%, < LOD - 6.0%, and 0.5-2.1% of total fatty acids, respectively. All samples contained high levels of 3-MCPD fatty acid esters that were determined after releasing the free 3-MCPD by methanolysis. The 3-MCPD levels in coffee creamers, cream aerosols, and bouillon cubes were in the range of 130-730 µg/kg (540-4480 µg/kg fat), 50-730 µg/kg (220-2880 µg/kg fat), and 380-670 µg/kg (2650-4840 µg/kg fat), respectively. The results showed that the refined and hydrogenated oils may represent a certain risk. The highest levels of 3-MCPD esters were found in a sample of refined palm oil (4170 µg/kg). Currently, there is no information available on how these 3-MCPD esters are metabolised, to which extent they are hydrolysed or biosynthesised in the body, to which extent they are deposited in tissues, and how they influence the properties and functions of tissues (if they really do it).

Keywords: coffee creamers; cream aerosols; bouillon cubes; fatty acids composition; trans-fatty acids; chloropropanols; 3-chloropropane-1,2-diol; 3-MCPD; 3-MCPD esters; contaminants

Published: October 31, 2007  Show citation

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Karšulínová L, Folprechtová B, Doležal M, Dostálová J, Velíšek J. Analysis of the lipid fractions of coffee creamers, cream aerosols, and bouillon cubes for their health risk associated constituents. Czech J. Food Sci. 2007;25(5):257-264. doi: 10.17221/679-CJFS.
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References

  1. AOAC (1975): Official Methods of Analysis of the AOAC, 12th Ed. Association of Official Analytical Chemists, Washington.
  2. Basiron Y. (2005). Palm oil. In: Shahidi F. (ed.): Bailey's Industrial Oil and Fat Products. 6th Ed. Vol. 2. WileyInterscience, Hoboken: 333-422. Go to original source...
  3. Caponio F., Gomes T., Delcuratolo D. (2002): Qualitative and quantitative characterisation of the lipid fraction of bouillon cubes. European Food Research & Technology, 215: 200-203. Go to original source...
  4. Divinová V., Doležal M., Velíšek J. (2007): Free and bound 3-chloropropane-1,2-diol in coffee surrogates and malts. Czech Journal of Food Sciences, 25: 39-47. Go to original source...
  5. Divinová V., Svejkovská B., Doležal M., Velíšek J. (2004): Determination of free and bound 3-chloropropane-1,2-diol by gas chromatography with mass spectrometric detection using deuterated 3-chloropropane-1,2-diol as internal standard. Czech Journal of Food Sciences, 22: 182-189. Go to original source...
  6. Doležal M., Chaloupská M., Divinová V., Svejkovská B., Velíšek J. (2005): Occurrence of 3-chloropropane-1,2-diol and its esters in coffee. European Food Research & Technology, 221: 221-225. Go to original source...
  7. Dietary Guidelines for Americans (2005): USDA, January 2005. Available at http://www.health.gov/dietaryguidelines/dga2005/document/
  8. EC (2001): European Commission Regulation No. 466/2001. Setting maximum levels for certain contaminants in foodstuffs. Official Journal of the European Communities L77/1, 16 March. Office for Official Publications of the European Communities, Luxembourg.
  9. EURODIET (2000): Eurodiet Reports 2000. Available at http://eurodiet.med.uoc.gr/
  10. Firestone D. (2005): Olive Oil. In: Shahidi F. (ed.): Bailey's Industrial Oil and Fat Products. 6th Ed. Vol. 2. Wiley-Interscience, Hoboken: 303-328. Go to original source...
  11. Guidance for Industry and Fda (2005): FY 2005 MDUFMA, Small Business Qualification, Worksheet and Certification. Available at http://www.fda.gov/cdrh/mdufma/guidance/2005.pdf
  12. Hamlet C.G., Sadd P.A. (2004): Chloropropanols and their esters in cereal products. Czech Journal of Food Sciences (Special Issue), 22: 229-262. Go to original source...
  13. IUPAC (1964): Standard Methods of the Oils and Fats, Division of the I.U.P.A.C. Met. I. B., 25th Ed. Butterworths, London.
  14. JECFA (2001): Joint FAO/WHO Expert Committee on Food Additives. 57 th Meeting, 5-14 June 2001, Rome.
  15. Mozaffarian D., Katan M.B., Ascherio A., Stampfer M.J., Willett W.C. (2006): Trans fatty acids and cardiovascular disease. New England Journal of Medicine, 354: 1601-1613. Go to original source... Go to PubMed...
  16. Nollet L.M.L. (1996): Handbook of Food Analysis. Vol. 1. Dekker, New York.
  17. SCF (2001): Opinion of the Scientific Committee on Food on 3-monochloro-propane-1,2-diol (3-MCPD) updating the SCF opinion of 1994. Adopted on 30 May 2001.
  18. Svejkovská B., Novotný O., Divinová V., Réblová Z., Doležal M., Velíšek J. (2004): Esters of 3-chloropropane-1,2-diol in foodstuffs. Czech Journal of Food Sciences, 22: 190-196. Go to original source...
  19. WHO (2004): Gold strategy on diet, physical activity and health, WHA57.17, Geneva. Available at www. dpaslac.org/uploads/1164807694.pdf
  20. Zelinková Z., Svejkovská B., Velíšek J., Doležal M. (2006): Fatty acids esters of 3-chloropropane-1,2diol in edible oils. Food Additives & Contaminants, 23: 1290-1298. Go to original source... Go to PubMed...
  21. Zelinková Z., Novotný O., Schůrek J., Velíšek J., Hajšlová J., Doležal M. (2007): New organochlorine contaminants in breast milk: 3-chloropropane-1,2-diol fatty acid esters. Food Additives & Contaminants, 24 (in press).

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