Czech J. Food Sci., 2006, 24(3):133-137 | DOI: 10.17221/3308-CJFS
Study of factors affecting acrylamide levels in model systems
- Food Research Institute, Bratislava, Slovak Republic
The factors important for the acrylamide formation in model systems were studied. The effects of two starch matrices (potato, wheat), the share of two monosaccharides (glucose and fructose) on the formation of acrylamide, and the impact of water addition were compared in model systems under isothermal conditions. Acrylamide was determined by GC/MS-NCI technique. The results showed that the water content is one of the most important factors in the formation of acrylamide, besides the reaction temperature and time. The minimum of acrylamide formation was observed at the water content between 25 and 40%; outside of this range, the acrylamide concentration was higher. The presence of starch reduced the amount of acrylamide formed from asparagine and saccharide, moreover, the effects of potato and wheat starches were similar. Fructose was more effective for the acrylamide formation in comparison with glucose. The combined contribution of glucose and fructose in the mixture with asparagine and starch to the acrylamide level corresponded to the sum of separate contributions of saccharides only at the middle content of added water.
Keywords: acrylamide; water content; GC-MS; Maillard reaction
Published: June 30, 2006 Show citation
References
- BECALSKI A., LAU B.P.Y., LEWIS D., SEAMAN S.W. (2003): Acrylamide in food: Occurrence, sources, and modelling. Journal of Agricultural and Food Chemistry, 51: 802-808.
Go to original source...
Go to PubMed...
- MATTHAUS B., HAASE N.U., VOSMANN K. (2004): Factors affecting the concentration of acrylamide during deep-fat frying of potatoes. European Journal of Lipid Science and Technology, 106: 793-801.
Go to original source...
- MOTTRAM D.S., WEDZICHA B.L., DODSON A.T. (2002): Food Chemistry: Acrylamide is formed in the Maillard reaction. Nature, 419: 448-449.
Go to original source...
Go to PubMed...
- ROBARGE T., PHILLIPS E., CONOLEY M.: Optimizing the analysis of acrylamide in food by quadrupole GC/MS. Application Note #9195, Thermo Electron Corporation, Austin, TX; http://www.thermo.com/com/cda/products/product_application_details/1,1063,11640,00.html.
- ROBERT F., VUATAZ G., POLLIEN P., SAUCY F., ALONSO M.-I., BAUWENS I., BLANK I. (2004): Acrylamide formation from asparagine under low-moisture Maillard reaction conditions. 1. Physical and chemical aspects in crystalline model systems. Journal of Agricultural and Food Chemistry, 52: 6837-6842.
Go to original source...
Go to PubMed...
- ROBERT F., VUATAZ G., POLLIEN P., SAUCY F., ALONSO M.-I., BAUWENS I., BLANK I. (2005): Acrylamide formation from asparagine under low-moisture Maillard reaction conditions. 2. Crystalline vs. amorphous model systems. Journal of Agricultural and Food Chemistry, 53: 4628-4632.
Go to original source...
Go to PubMed...
- STADLER R.H., BLANK I., VARGA N., ROBERT F., HAU J., GUY P.A., ROBERT M.-C., RIEDIKER S. (2002): Food chemistry: Acrylamide from Maillard reaction products. Nature, 419: 449-450.
Go to original source...
Go to PubMed...
- TAEYMANS D., ANDERSSON A., ASHBY P., BLANK I., GONDÉ P., VAN EIJCK P., FAIVRE V., LALLJIE S.P.D., LINGNERT H., LINDBLOM M., MATISSEK R., MULLER D., STADLER R.H., STUDER A., SILVANI D., TALLMADGE D., THOMPSON G., WHITMORE T., WOOD J., ZYZAK D. (2005): Acrylamide: Update on selected research activities conducted by European food and drink industry. Journal of AOAC International, 88: 234-241.
Go to original source...
Go to PubMed...
- TAEYMANS D., WOOD J., ASHBY P., BLANK I., STUDER A., STADLER R.H., GONDÉ P., VAN EIJCK P., LALLJIE S., LINGNERT H., LINDBLOM M., MATISSEK R., MULLER D., TALLMADGE D., O'BRIEN J., THOMPSON S., SILVANI D., WHITMORE T. (2004): A review of acrylamide: An industry perspective on research, analysis, formation, and control. Critical Revue in Food Science and Nutrition, 44: 323-347.
Go to original source...
Go to PubMed...
- TAREKE E., RYDBERG P., KARLSSON P., ERIKSSON S., TORNQVIST M. (2002): Analysis of acrylamide, a carcinogen formed in heated foodstuffs. Journal of Agricultural and Food Chemistry, 50: 4998-5006.
Go to original source...
Go to PubMed...
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