Czech J. Food Sci., 2005, 23(6):230-239 | DOI: 10.17221/3396-CJFS

Oxidative changes of vegetable oils during microwave heating

Jana Dostálová, Pavel Hanzlík, Zuzana Réblová, Jan Pokorný
Department of Food Chemistry and Analysis, Faculty of Food and Biochemical Technology, Institute of Chemical Technology in Prague, Prague, Czech Republic

The oxidative stabilities of pork lard, sunflower, zero-erucic rapeseed, peanut and high-oleic peanut oils were tested under microwave heating conditions. Vegetable oils and lard were heated in a microwave oven for up to 40 min between 25°C and 200°C. The peroxide value, the contents of conjugated dienoic and trienoic acids, and polymers were used as markers of lipid degradation. Sunflower oil was found the least stable oil because of a high polyenoic acid content and a low content of γ-tocopherol. Rapeseed oil was more stable because of a lower polyenoic acid content and a high γ-tocopherol level. Conventional peanut oil was relatively stable, but substantially less stable than high-oleic peanut oil. Pork lard and high-oleic peanut oil formed only low levels of polymers due to a low polyenoic acid content.

Keywords: microwave heating; oxidation; polymerisation; pork lard; vegetable oils

Published: December 31, 2005  Show citation

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Dostálová J, Hanzlík P, Réblová Z, Pokorný J. Oxidative changes of vegetable oils during microwave heating. Czech J. Food Sci. 2005;23(6):230-239. doi: 10.17221/3396-CJFS.
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References

  1. ALBI T., LANZON A., GUINDA A., LEON M., PEREZ-CAMINO M.C. (1997a): Microwave and conventional heating effects on thermo-oxidative degradation of edible fats. Journal of Agricultural and Food Chemistry, 45: 3795-3798. Go to original source...
  2. ALBI T., LANZON A., GUINDA A., PEREZ-CAMINO M.C., LEON M. (1997b): Microwave and conventional heating effects on some physical and chemical parameters of edible fats. Journal of Agricultural Food Chemistry, 45: 3000-3003. Go to original source...
  3. BARRINGER S.A. (1995): Experimental and predictive heating rates of microwave food systems. Dissertation Abstracts International B, 55: 4188.
  4. BEDNÁŘOVÁ K. (2004): Změny lipidů během mikrovlnného ohřevu potravin. [MSc. Diploma Work.] Institute of Chemical Technology, Prague.
  5. CAPONIO F., PASQUALONE A., BILANCIA M.T., SACCO D., DELCURATOLO D., GOMES T. (2001): Measure of thermo-oxidation of vegetable oils microwave-heated in model systems. Industrie Alimentari, 40: 628-632.
  6. COSSIGNANI L., SIMONETTI M.S., NERI A., DAMIANI P. (1998): Changes in olive oil composition due to microwave heating. Journal of American Oil Chemists' Society, 75: 931-937. Go to original source...
  7. FARAG R.S., HEWEDI F.M., ABU-RAILA S.H., EL-BAROTY G.S. (1992): Comparative study of the deterioration of oils by microwave and conventional heating. Journal of Food Protection, 55: 722-727. Go to original source... Go to PubMed...
  8. GERTZ C. (2004): Optimising the baking and frying process using oil-improving agents. European Journal of Lipid Science and Technology, 106: 736-745. Go to original source...
  9. HASSANEIN M.M., EL-SHAMI S.M., EL-MALLAH M.H. (2003): Changes occurring in vegetable oils composition due to microwave heating. Grasas y Aceites, 54: 343-349. Go to original source...
  10. KAMAL-ELDIN A. (2003): Lipid Oxidation Pathways. AOCS Press, Champaign. Go to original source...
  11. KIM E.-M., JOO K.-J. (1995): Oxidative stability of fatty acids and tocopherols in the fats and oils during microwave heating. Journal of Korean Society of Foods and Nutrition, 24: 234-241.
  12. KNAUFT D.A., MOORE K.M., GORBET D.W. (1993): Further studies on the inheritence of fatty acid composition in peanut. Peanut Science, 20: 74-76. Go to original source...
  13. MARINOVA E., YANISHLIEVA N., TONEVA A., PSOMIADOU E., TSIMIDOU M. (2001): Changes in the oxidation stability and tocopherol content in oils during microwave heating. Rivista Italiana delle Sostanze Grasse, 78: 529-533.
  14. MÁRQUEZ-RUIZ G., DOBARGANES M.C. (1996): Nutritional and physiological effects of used frying fats. In: PERKINS E.G., ERICKSON M.D. (eds): Deep Frying. AOCS Press, Champaign: 160-182.
  15. O'KEEFE S.F., WILEY V.A., KNAUFT D.A. (1993): Comparison of oxidative stability of high- and normal-oleic peanut oils. Journal of American Oil Chemists' Society, 70: 489-492. Go to original source...
  16. PAQUOT C., HAUTFENNE A. (1987): Standard methods for the analysis of oils, fats and derivatives. 7 th Ed. Blackwell Scientific Publication, Oxford. Go to original source...
  17. PARKÁNYIOVÁ L., TROJÁKOVÁ L., RÉBLOVÁ Z., ZAINUDDIN A., NGUYEN H.T.T., SAKURAI H., MIYAHARA M., POKORNÝ J. (2000): Resistance of high-oleic acid peanut oil against autoxidation under storage and deep frying conditions. Czech Journal of Food Sciences, 18 (Special Issue): 125-126.
  18. POKORNÝ J. (1987): Major factors affecting the autoxidation of lipids. In: CHAN H.W.-S. (ed.): Autoxidation of Unsaturated Lipids. Academic Press, London: 141-206.
  19. POKORNÝ J. (1989): Flavor chemistry of deep fat frying in oil. In: MIN D.B., SMOUSE T.H. (eds): Flavor Chemistry of Lipid Foods. The American Oil Chemists' Society, Champaign: 113-155.
  20. POKORNÝ J., MARE© E. (1958): Oxidace ethylesterů mastných kyselin a thermický rozklad oxydačních produktů. In: Sborník V©CHT v Praze, Oddíl Fakulty Potravinářské Technologie, 2: 221-248.
  21. POKORNÝ J., SCHMIDT ©. (2001): Natural antioxidants functionality during food processing. In: POKORNÝ J., YANISHLIEVA N., GORDON M. (eds): Antioxidants in Food. Practical Applications. Woodhead Publishing Ltd., Cambridge: 331-354. Go to original source...
  22. PROSETYA H., DATTA A. (1991): Batch microwave heating of liquids; an experimental study. Journal of Microwave Power and Electromagnetic Energy, 26: 215-226. Go to original source...
  23. RÉBLOVÁ Z. (1999): Degradace lipidů za vysoké teploty. [PhD. Thesis.] Institute of Chemical Technology, Prague.
  24. REGULSKA-ILOW B., ILOW R., SZYMCZAK J. (1997): Evaluation of lipid oxidation and hydrolysis of vegetable fats during conventional and microwave cooking. Bromatologia, Chimia, Toksykologia, 30: 137-141.
  25. SAKURAI H., YAMAKI T., KUMAGAI H., NGUYEN H.T.T., ZAINUDDIN A., TROJÁKOVÁ L., POKORNÝ J. (1999): Oxidative stability of conventional and high-oleic peanut oils with aspect of their application in functional foods. In: Proceedings on Functional Foods, Technical University, Budapest: 784-790.
  26. SEKRETÁR S., ZELENKA M., SCHMIDT ©. (1997): Effects of natural antioxidants on light and microwave accelerated oxidation in lard. Chemické listy, 91: 711-712.
  27. SEKRETÁR S., SIVÁKOVÁ J., HORODNÍKOVÁ D., SCHMIDT ©. (1998): Externé faktory oxidácie jedlých tukov a olejov. In: Sborník přednáąek XXXVI. semináře z technologie a analytiky tuků, Strakonice: 154-157.
  28. SEKRETÁR S., SCHMIDT ©., NIKLOVÁ I., KOVÁČ M. (2000): Degradation effects of microwave heating on fats. Czech Journal of Food Sciences, 18 (Special Issue): 127-128.
  29. TAN C.P., CHE MAN Y.B., JINAP S., YUSOFF M.S.A. (2001): Effects of microwave heating on changes in chemical and thermal properties of vegetable oils. Journal of American Chemical Society, 78: 1227-1232. Go to original source...
  30. VIEIRA T.M.F.S., REGITANO-D'ARCE M.A.B. (1999): Ultraviolet spectrophotometrie evaluation of corn oil oxidative stability during microwave heating and oven text. Journal of Agricultural and Food Chemistry, 47: 2203-2206. Go to original source... Go to PubMed...
  31. VIEIRA T.M.F.S., REGITANO-D'ARCE M.A.B. (2001): Canola oil thermal oxidation during oven test and microwave heating. Lebensmittel-Wissenschaft und -Technologie, 34: 215-219. Go to original source...
  32. VITRAC O., TRYSTRAM G., RAOULT-WACK A.-L. (2003): Procédé de friture et produits frits. In: GRAILLE J. (ed.): Lipides et Corps Gras Alimentaires. Lavoisier, London, Paris, New York: 231-273.
  33. YOSHIDA H. (1993): Influence of fatty acids of different unsaturation in the oxidation of purified vegetable oils during microwave irradiation. Journal of Science of Food and Agriculture, 62: 41-47. Go to original source...
  34. YOSHIDA H., HIRAKAWA Y., ABE S., MIZUSHINA Y. (2002): The content of tocopherols and oxidative quality of oils prepared from sunflower seeds roasted in a microwave oven. European Journal of Lipid Science and Technology, 104: 116-122. Go to original source...
  35. YOSHIDA H., HIRAKAWA Y., TOMIYAMA Y., MITSUSHINA Y. (2003): Effects of microwave treatment on the oxidative stability of peanut oils and the molecular species of their triacylglycerols. European Journal of Lipid Science and Technology, 105: 351-358. Go to original source...
  36. YOSHIDA H., HIROOKA N., KAJIMOTO G. (1991): Microwave heating effects on relative stabilities of tocopherols in oils. Journal of Food Science, 56: 1042-1046. Go to original source...
  37. YOSHIDA H., KAJIMOTO G., EMURA S. (1993): Antioxidant effects of d-tocopherols at different concentration in oils during microwave heating. Journal of American Oil Chemists' Society, 70: 989-995. Go to original source...
  38. YOSHIDA H., KONDO I., KAJIMOTO G. (1992): Participation of free fatty acids in the oxidation of purified soybean oil during microwave heating. Journal of American Oil Chemists' Society, 69: 1136-1140. Go to original source...
  39. ZAINUDDIN A., PARKÁNYIOVÁ J., PARKÁNYIOVÁ L., POKORNÝ J., SAKURAI H. (2004): Comparison of oxidative resistance of traditional and high-oleic peanut oils in emulsions. Czech Journal of Food Sciences, 22 (Special Issue): 136-138. Go to original source...
  40. ZHANG G.Y., GUO Z.Y., LI L., CAI M.Y. (2000): Comparative study of the effects of microwaves and conventional heating on vegetable oil temperature and oxidative stability. Food Science, China, 21: 21-29.

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