Czech J. Food Sci., 2004, 22(10):S64-S67 | DOI: 10.17221/10613-CJFS

Phenolic compounds as cross-links of plant derived polysaccharides

M. Bunzel, J. Ralph, H. Steinhart
1 Institute of Biochemistry and Food Chemistry, University of Hamburg, Hamburg, Germany
2 US Dairy Forage Research Center, USDA-Agricultural Research Service, Madison, USA

Plant cell wall polysaccharides are partially cross-linked via phenolic compounds. As shown in the past, the most important phenolic compounds to cross-link plant cell-wall polysaccharides are ester-linked ferulic acid dimers, but p-coumarate dimers were also shown to be potential cross-linking compounds. Recently, ferulic acid dimers were identified and quantified in a range of cereal grains. The isolation of 8-O-4-dehydrodiferulic aciddiarabinoside from maize bran shows that diferulic acids are able to form intermolecular cross-links between arabinoxylans. The more recently identified sinapic acid dehydrodimers and ferulic acid dehydrotrimers provide additional contributions to building up a strong network of plant cell wall polysaccharides.

Keywords: plant cell walls; arabinoxylans; ferulic acid; ferulate dimers and trimers; sinapate dimers

Published: December 31, 2004  Show citation

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Bunzel M, Ralph J, Steinhart H. Phenolic compounds as cross-links of plant derived polysaccharides. Czech J. Food Sci. 2004;22(Special Issue):S64-67. doi: 10.17221/10613-CJFS.
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