Czech J. Food Sci., 2003, 21(5):185-191 | DOI: 10.17221/3497-CJFS
Crystals in hard candies
- 1 Department of Carbohydrate Chemistry and Technology and
- 2 Department of Glass and Ceramics, Institute of Chemical Technology, Prague, Czech Republic
- 3 Universidade de Aveiro, Departamento de Química, Portugal$2
The main purpose of the contribution presented here is the study of the glassy state and the presence of crystals in hard candies. Hard candies are non-chocolate sweets usually made of sucrose and glucose or of maltose syrup. They can also be made of alditols, used in sugar-free hard candies. In hard candies, carbohydrates or alditols are in amorphous state. Crystallisation in the glassy state of hard candies occurs as a result of a bad formulation, processing or storage and can be detrimental to the product quality. Differential scanning calorimetry was used to determine the glass transition temperature Tg and the amount of crystals. Polarising microscopy was used to show the undesirable presence of crystals in samples of hard candies. The carbohydrates composition of the samples was determined by HPLC and the moisture content in each sample was evaluated by Karl Fisher method.
Keywords: hard candy; the glass transition; crystallisation; differential scanning calorimetry; polarising microscopy
Published: October 31, 2003 Show citation
References
- A L.J. (1995): Hard candy, formulations, variations and effects. Manuf. Conf., 75: 33-36.
- B M. (1987): Technická mineralogie. Skripta. VŠCHT, Praha.
- G P., H R.W. (1996): The influence of corn (glucose) syrup oligosaccharides on transition of amorphous sucrose. In: Int. Workshop Industrial Crystallization, Sept. 12-13, Bremen: 34-41.
- G P., H R.W. (1998): Corn syrup solids and their saccharide fractions affect crystallization of amorphous sucrose. J. Food Sci., 63: 523-528.
Go to original source...
- K C.J., M N W., M J. R. (2000): Isothermal and non-isothermal crystallization in amorphous sucrose and lactose at low moisture contents. Carbohydr. Res., 329: 423-430.
Go to original source...
Go to PubMed...
- L H., S L. (1988): Collapse phenomena - A unifying concept for interpreting the behaviour of low moisture foods.In: B J.M.V., M J.R. (eds): Food Structure - Its Creation and Evaluation. Bu erworths, London: 149-180.
Go to original source...
- L C.E. (1997): DSC study of honey granulation stored at various temperatures. Food Res. Int., 30: 683-688.
Go to original source...
- R A., S T. (1983): Thermal behaviour of carbohydrates studied by heat flow calorimetry. J. Thermal. Anal., 28: 95-108.
Go to original source...
- R Y. (1993): Melting and the glass transition of low molecular weight carbohydrates. Carbohydr. Res., 238: 39-48.
Go to original source...
- R Y.H. (1995): Phase Transition in Foods. Academic Press, San Diego.
- S K.D., L S.T., K H.I. (1998): Effect of organic acids on the sugar composition of sucrose candies. Food Sci. Biotechnol., 7: 100-106.
- S L., L H. (1991): Beyond water activity: recent advances based on an alternative approach to the assessment of food quality and safety. Crit. Rev. Food Sci. Nutr., 30: 115-360
Go to original source...
Go to PubMed...
This is an open access article distributed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International (CC BY NC 4.0), which permits non-comercial use, distribution, and reproduction in any medium, provided the original publication is properly cited. No use, distribution or reproduction is permitted which does not comply with these terms.