Czech J. Food Sci., 2001, 19(2):73-80 | DOI: 10.17221/6579-CJFS

Application of electrodialysis for lactic acid recovery

V. Hábová, K. Melzoch, M. Rychtera, L. Přibyl, V. Mejta
1 Institute of Chemical Technology, Prague Department of Fermentation Chemistry and Bioengineering
2 Department of Inorganic Technology, Prague, Czech Republic

The paper deals with the possibility of using two-stage electrodialysis for recovery of lactic acid from model solutions and from fermentation broth. In the first step lactate was concentrated with desalting electrodialysis using ion exchange membranes Ralex (Mega,Czech Republic). The highest final concentration of 111 g/l was reached in the concentrate, it means an increase more than 2.5-times in comparison with the initial concentration. At the most 2 g of lactate per litre remained in the feed. The second step was the electroconversion of sodium lactate to lactic acid by water-splitting electrodialysis with the bipolar membranes Neosepta (Tokuyama Corp.,Japan). The final lactic acid concentration of 157 g/l was reached in the diluate. Total required energy in both electrodialysis processes consisting of the energy consumption for lactate transfer and for its electroconversion to lactic acid was 142 Wh/mol. The fermentation broth was decolourised before electrodialysis experiments. The best decolourisation capacity was shown by granulated active charcoal filled in the column operated by a slow flow of broth.

Keywords: lactic acid recovery; electrodialysis; desalting electrodialysis; water-splitting electrodialysis; decolourisation

Published: April 30, 2001  Show citation

ACS AIP APA ASA Harvard Chicago Chicago Notes IEEE ISO690 MLA NLM Turabian Vancouver
Hábová V, Melzoch K, Rychtera M, Přibyl L, Mejta V. Application of electrodialysis for lactic acid recovery. Czech J. Food Sci. 2001;19(2):73-80. doi: 10.17221/6579-CJFS.
Download citation

References

  1. ASENJO J.A. (1990): Separation Processes in Biotechnology. Marcel Dekker, Inc., New York.
  2. BLEHA M., CIVÍN V., NOVÁK L. (1988): Elektrodialýza. In: Membránové procesy. Course Proc., 17.–21. 10. 1988, Modra: 161–179, 239–256. Go to original source...
  3. BOYAVAL P., CORRE C., TERRE S. (1987): Continuous lactic acid fermentation with concentrated product recovery by ultrafiltration and electrodialysis. Biotechnol. Lett., 9: 207–212. Go to original source...
  4. BUCHTA K. (1983): Lactic Acid. In: DELLWEG H. (Ed.): Biotechnology. Vol. 3. Verlag Chemie, Weinheim: 410–417.
  5. CZYTKO M., ISHII K., KAWAI K. (1987): Continuous glucose fermentation for lactic acid production: Recovery of acid by electrodialysis. Chem. Ing. Tech., 59: 952–954. Go to original source...
  6. GLASSNER D.A., DATTA R. (1990): Process for production and purification of lactic acid. EP 0 393 818 A1.
  7. HERIBAN V., SITKEY V., ŠTURDÍK E., SLÁMA V., TIBENSKÝ V. (1993): Fermentaèná produkcia kyseliny mlieènej. Kvas. prùm., 39: 197–203. Go to original source...
  8. HERIBAN V., ŠKÁRA J., ŠTURDÍK E., ILAVSKÝ J. (1993): Isolation of free lactic acid using electrodialysis. Biotech. Technol., 7: 63–68. Go to original source...
  9. HONGO M., NOMURA Y., IWAHARA M. (1986): Novel method of lactic acid production by electrodialysis fermentation. Appl. Environ. Microbiol., 52: 314–319. Go to original source... Go to PubMed...
  10. JANDOVÁ I. (1996): Odstraòování solí z vodných roztokù elektrodialýzou. [Diploma thesis.] ICT Prague.
  11. KAŠÈÁK J. S., KOMÍNEK J., ROEHR M. (1996): Lactic Acid. In: ROEHR M. (Ed.): Biotechnology. Vol. 6 – Products of primary metabolism. VCH, Weinheim: 294–306.
  12. KRAVJAROVÁ D. (1991): Elektrodialýza a jej aplikácie v potravinárskom priemysle. Prùm. Potrav., 42: 400–401.
  13. LEE E.G., MOON S.-H., CHANG Y. K., YOO I.-K., CHANG H.N. (1998): Lactic acid recovery using two-stage electrodialysis and its modelling. J. Membr. Sci., 145: 53–66. Go to original source...
  14. MATEUS M., SANTOS J.A.L., CABRAL J.M.S. (1993): Membrane Separation Processes. In: KENNEDY J.F., CABRAL J.M.S. (Ed.): Recovery Processes for Biological Materials. John Wiley & Sons, Chichester: 177–222.
  15. MULDER M. (1991): Basic Principles of Membrane Techno/ logy. Kluwer Acad. Publ., Dordrecht: 270–280. Go to original source...
  16. NOMURA Y., IWAHARA M., HOHGO M. (1987): Lactic acid production by electrodialysis fermentation using immobilized growing cells. Biotechnol. Bioeng., 30: 788–793. Go to original source... Go to PubMed...
  17. SVOBODOVÁ J. (1999): Ovìøení vybraných druhù mléèných bakterií v diskontinuálních a kontinuálních fermentacích. [Diploma thesis.] Prague, Inst. Chem. Technol..
  18. VICK ROY T.B. (1985): Lactic Acid. In: YOUNG M.M. (Ed.): Comprehensive Biotechnology. Pergamon Press, New York: 761–775.
  19. YAO P.-X., TODA K. (1990): Lactic acid production in electrodialysis culture. J. Gen. Appl. Microbiol., 36: 111–125. Go to original source...

This is an open access article distributed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International (CC BY NC 4.0), which permits non-comercial use, distribution, and reproduction in any medium, provided the original publication is properly cited. No use, distribution or reproduction is permitted which does not comply with these terms.